Thiazole

  • CasNo：288-47-1
  • purity：99%
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Details

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  • Molecular Formula:C3H3NS
  • Molecular Weight:85.1295
  • Appearance/Colour:colourless or pale yellow liquid 
  • Vapor Pressure:21.6mmHg at 25°C 
  • Melting Point:-33 °C 
  • Refractive Index:n20/D 1.538(lit.)  
  • Boiling Point:116.5 °C at 760 mmHg 
  • PKA:2.44(at 20℃) 
  • Flash Point:26 ºC 
  • PSA：41.13000 
  • Density:1.18 g/cm3 
  • LogP:1.14310 

Thiazole(Cas 288-47-1) Usage

Air & Water Reactions

Slightly water soluble.

Reactivity Profile

Thioisocyanates, such as Thiazole, are incompatible with many classes of compounds, reacting exothermically to release toxic gases. Reactions with amines, aldehydes, alcohols, alkali metals, ketones, mercaptans, strong oxidizers, hydrides, phenols, and peroxides can cause vigorous releases of heat.

General Description

Thiazole, also known as 3-Azathiophene, is a heterocyclic compound featuring a five-membered ring containing both sulfur and nitrogen atoms. It serves as a key structural motif in various pharmacologically active compounds and coordination complexes, demonstrating versatile reactivity in synthetic chemistry, such as participating in metal-assisted condensation reactions and forming derivatives with potential anti-inflammatory and analgesic properties.

Definition

A colorless volatile liquid, a beterocyclic compound with a five-membered ring containing three carbon atoms, one nitrogen atom, and one sulfur atom. It resembles PYRIDINE in its reactions.

Aroma threshold values

Detection: 3.1 ppm

InChI:InChI=1/C3H3NS/c1-2-5-3-4-1/h1-3H

288-47-1 Relevant articles

-

Iversen

, p. 484 (1972)

-

An Efficient Synthesis of 1,3-Thiazole

Brandsma, L.,Jong, R. L. P. de,VerKruijsse, H. D.

, p. 948 - 949 (1985)

The cyclocondensation of methyl dithioca...

Characteristic flavor formation of thermally processed N-(1-deoxy-α-D-ribulos-1-yl)-glycine: Decisive role of additional amino acids and promotional effect of glyoxal

Zhan, Huan,Cui, Heping,Yu, Junhe,Hayat, Khizar,Wu, Xian,Zhang, Xiaoming,Ho, Chi-Tang

, (2021/09/28)

The role of amino acids and α-dicarbonyl...

PYRAZINE DERIVATIVE AND APPLICATION THEREOF IN INHIBITING SHP2

-

, (2022/01/23)

-

Protodeboronation of (Hetero)Arylboronic Esters: Direct versus Prehydrolytic Pathways and Self-/Auto-Catalysis

Hayes, Hannah L. D.,Wei, Ran,Assante, Michele,Geogheghan, Katherine J.,Jin, Na,Tomasi, Simone,Noonan, Gary,Leach, Andrew G.,Lloyd-Jones, Guy C.

supporting information, p. 14814 - 14826 (2021/09/13)

The kinetics and mechanism of the base-c...

Photocatalytic Generation of 2-Azolyl Radicals: Intermediates for the Azolylation of Arenes and Heteroarenes via C-H Functionalization

Arora, Amandeep,Weaver, Jimmie D.

supporting information, p. 3996 - 3999 (2016/08/30)

The 2-azolyl radical, generated from 2-b...

288-47-1 Process route

D-glucose
50-99-7

D-glucose

GLUTATHIONE
70-18-8

GLUTATHIONE

1,3-thiazole
288-47-1

1,3-thiazole

Thiophene-2-thiol
7774-74-5

Thiophene-2-thiol

Tetrahydrothiophen-3-one
1003-04-9

Tetrahydrothiophen-3-one

furfural
98-01-1

furfural

2,5-DIMETHYLTHIOPHENE
638-02-8

2,5-DIMETHYLTHIOPHENE

5-Methylfurfural
620-02-0

5-Methylfurfural

1-(2-furyl)-1-ethanone
1192-62-7,80145-44-4

1-(2-furyl)-1-ethanone

2-methylthiophene-3-thiol
2527-76-6

2-methylthiophene-3-thiol

2-Acetylpyrrole
1072-83-9

2-Acetylpyrrole

2-methylfuran-3-thiol
28588-74-1

2-methylfuran-3-thiol

Conditions
Conditions Yield
In water; at 160 ℃; for 2h; pH=7.5;
N-(1-deoxy-D-erythro-2-pentulos-1-yl)glycine

N-(1-deoxy-D-erythro-2-pentulos-1-yl)glycine

1,3-thiazole
288-47-1

1,3-thiazole

furfural
98-01-1

furfural

thiophene-2-carbaldehyde
98-03-3

thiophene-2-carbaldehyde

4,5-Dihydro-2-methylthiophen-3-(2H)-on
74015-70-6,13679-85-1

4,5-Dihydro-2-methylthiophen-3-(2H)-on

5-Methylfurfural
620-02-0

5-Methylfurfural

5-methylthiophene-2-carboxaldehyde
13679-70-4

5-methylthiophene-2-carboxaldehyde

2-Acetylthiazole
24295-03-2,260998-74-1

2-Acetylthiazole

2-butyrylthiophene
5333-83-5

2-butyrylthiophene

perillene
539-52-6

perillene

benzofuran, 4,7-dimethyl-
28715-26-6

benzofuran, 4,7-dimethyl-

2,5-thiophenedicarboxaldehyde
932-95-6

2,5-thiophenedicarboxaldehyde

Conditions
Conditions Yield
With L-Cysteine; at 100 ℃; for 2h;

288-47-1 Upstream products

  • 40018-26-6
    40018-26-6

    1,4-dithiane-2,5-diol

  • 50-00-0
    50-00-0

    formaldehyd

  • 3034-52-4
    3034-52-4

    2-chlorothiazole

  • 53089-10-4
    53089-10-4

    2,2-diethoxy-1-formylaminoethane

288-47-1 Downstream products

  • 24295-03-2
    24295-03-2

    2-Acetylthiazole

  • 5304-34-7
    5304-34-7

    2-(3-thiazolium)-1-phenylethanone bromide

  • 3034-53-5
    3034-53-5

    2-bromo-1,3-thiazole

  • 14190-59-1
    14190-59-1

    1,3-thiazole-2-carboxylic acid

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